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41.
Short-term flow fluctuations in the southern central part of Onagawa Bay were examined using long-term mooring and hydrographic data observed during the period from May 2013 to April 2014. The short-term flow fluctuations were dominant in the periodic bands of 15–27 days and shorter than 10 days. The principal and minor components of these flow fluctuations were respectively along and across the local isobaths, which are almost parallel in the north direction. The northward flow fluctuations along the local isobaths were correlated with the northeastward wind fluctuations in both periodic bands, and these correlations were more evident from fall to winter. On the basis of these results, the northward flows are regarded as wind-induced barotropic coastal jets. On other hand, the eastward flow fluctuations across the local isobaths were related to inflow and outflow via the bay mouth or the Izushima Channel. Inflow and outflow with reverse flow at lower depths formed in summer, but those with vertically uniform flow tended to form in winter. The main summertime inflow and outflow were driven by horizontal gradients in density. These permit us to regard the main summertime inflow and outflow as gravitational circulation. Also, the summertime inflow can be intermittently caused by internal waves.  相似文献   
42.
We have determined chlorophyll a (Chla) concentration, primary productivity, cell density and species composition of diatoms, and the number of microzooplankton at the surface in the subarctic North Pacific in January 1996. The wet weight of copepods obtained by vertical tows from 150 m to the surface was also measured during the cruise. Chla concentration and primary productivity tended to be higher in the region west of 180°, the western subarctic North Pacific (WSNP), than east of 180°, the eastern subarctic North Pacific (ESNP). The same results were observed for the total diatom cell densities and for the genera Thalassiosira and Denticulopsis. Significant linear relationships were observed between the Thalassiosira cell density and Chla concentration and primary productivity, indicating that Thalassiosira contributes to the high-WSNP and low-ESNP distribution patterns of Chla concentration and primary productivity. Moreover, naked ciliate abundance tended to be lower in the WSNP than in the ESNP, whereas copepod biomass showed an inverse trend. Significantly negative Spearman rank correlations were found between the Thalassiosira cell density and the number of naked ciliates and between the number of naked ciliates and the wet weight of copepods. These results indicate that copepod grazing indirectly controls Thalassiosira cell density via predation on the naked ciliates. We conclude that the high copepod biomass in the WSNP is a factor controlling the high-WSNP and low-ESNP Thalassiosira abundance and hence Chla concentration and primary productivity patterns.  相似文献   
43.
孙萍 《海洋地质前沿》2008,24(11):41-43
贝尔加湖首次发现气体水合物是1997年贝加尔钻探计划(BDP)在盆地南部海底深度121m和161m处,气体成分主要是甲烷,8δC值范围为-68.2‰~-57.6‰,表明这些气体水合物是微生物成因的。最近,在盆地南部的Malenky泥火山和盆地中部的Kukuy K-2地区海底发现气体水合物,这些站点位于抬升地形带上,并且具有流体溢出口特征。  相似文献   
44.
Hydrate-bearing sediment cores were retrieved from recently discovered seepage sites located offshore Sakhalin Island in the Sea of Okhotsk. We obtained samples of natural gas hydrates and dissolved gas in pore water using a headspace gas method for determining their molecular and isotopic compositions. Molecular composition ratios C1/C2+ from all the seepage sites were in the range of 1,500–50,000, while δ13C and δD values of methane ranged from ?66.0 to ?63.2‰ VPDB and ?204.6 to ?196.7‰ VSMOW, respectively. These results indicate that the methane was produced by microbial reduction of CO2. δ13C values of ethane and propane (i.e., ?40.8 to ?27.4‰ VPDB and ?41.3 to ?30.6‰ VPDB, respectively) showed that small amounts of thermogenic gas were mixed with microbial methane. We also analyzed the isotopic difference between hydrate-bound and dissolved gases, and discovered that the magnitude by which the δD hydrate gas was smaller than that of dissolved gas was in the range 4.3–16.6‰, while there were no differences in δ13C values. Based on isotopic fractionation of guest gas during the formation of gas hydrate, we conclude that the current gas in the pore water is the source of the gas hydrate at the VNIIOkeangeologia and Giselle Flare sites, but not the source of the gas hydrate at the Hieroglyph and KOPRI sites.  相似文献   
45.
The thermoelastic parameters of synthetic Mn3Al2Si3O12 spessartine garnet were examined in situ at high pressure up to 13 GPa and high temperature up to 1,100 K, by synchrotron radiation energy dispersive X-ray diffraction within a DIA-type multi-anvil press apparatus. The analysis of room temperature data yielded K 0 = 172 ± 4 GPa and K 0  = 5.0 ± 0.9 when V 0,300 is fixed to 1,564.96 Å3. Fitting of PVT data by means of the high-temperature third-order Birch–Murnaghan EoS gives the thermoelastic parameters: K 0 = 171 ± 4 GPa, K 0  = 5.3 ± 0.8, (?K 0,T /?T) P  = ?0.049 ± 0.007 GPa K?1, a 0 = 1.59 ± 0.33 × 10?5 K?1 and b 0 = 2.91 ± 0.69 × 10?8 K?2 (e.g., α 0,300 = 2.46 ± 0.54 × 10?5 K?1). Comparison with thermoelastic properties of other garnet end-members indicated that the compression mechanism of spessartine might be the same as almandine and pyrope but differs from that of grossular. On the other hand, at high temperature, spessartine softens substantially faster than pyrope and grossular. Such softening, which is also reported for almandine, emphasize the importance of the cation in the dodecahedral site on the thermoelastic properties of aluminosilicate garnet.  相似文献   
46.
This study was conducted to determine the phytotoxicity of 6 nm γ-Fe2O3 nanoparticles (IONPs) in terms of root elongation and the physiological performance of rice plants. Rice seeds (Oryza sativa L. var. Koshihikari) exposed to IONPs at 500, 1,000 and 2,000 mg/L, had a significantly higher root elongation than the control and its bulk counterparts (IOBKs), indicating that the effect can be nanospecific. In a 14-week greenhouse pot experiment, the CO2 assimilation rate in IOBK and IONP-treated pots (500 and 1,000 mg/pot) decreased over time, with the decline (maximum 42.5 %) being less pronounced for IONPs, indicating that the effect cannot be inferred from the toxicity of nanoscale size iron oxide. Excessive adsorption of IONPs onto soil colloids with subsequent low water extractable iron was responsible for the unremarkable phytotoxic nature of IONPs in the rice plants. Amendment of IONPs coated with 20 mmol citric acid (IONPs-Cit) significantly diminished the CO2 assimilation rate and the decrease was similar to its bulk counterpart (IOBKs-Cit). However, maximum shoot growth inhibition (37 %) was associated with the application of IOBKs-Cit. It was concluded that massive accumulations of Fe plaque on the root surfaces of IOBKs-Cit treatments due to a decline in the pH of rhizoplane soils compared to the IONPs-Cit treatments were responsible for the remarkable shoot growth reduction. This study provided evidence of the phytotoxicity of γ-Fe2O3 nanoparticles, demonstrating the lower toxicity of nanosized iron oxide compared to a microsized preparation under reductive conditions.  相似文献   
47.
48.
The Asian monsoon is one of the largest climatic systems in the world, but age of its onset has been estimated differently ranging from the late Eocene to the Quaternary. We investigated the sedimentology and stable isotopic compositions of the upper Eocene Jiuziyan Formation, a terrestrial limestone unit in the Jianchuan basin, Yunnan Province in China. This limestone formation is restricted in several localities in the central part of the basin. Previously, this has been characterized as palustrine carbonate and the transition to the sublacustrine deposit of the overlying Shuanghe Formation was interpreted as the appearance of wetter climate during the late Eocene. Our observations of macro- and microfacies revealed sedimentary fabrics indicating rapid CaCO3 precipitation, such as dendritic calcite and calcified reed stems, which are unlikely to develop in a simple lacustrine setting. High carbonate content (mostly >90 %) and restricted distribution of the Jiuziyan limestone indicate a depositional setting spatially limited and isolated from clastic influx. These findings, together with clearly higher δ13C values (−0.7 ‰ to +6.9 ‰) and lower δ18O values (−14.6 ‰ to −10.5 ‰) than those of the Shuanghe Formation, indicate that the limestone was mainly travertine, carbonate formed from endogenic spring water. The elevated δ13C resulted from a large amount of CO2 degassing from spring water with high pCO2. In addition, the occurrence of centimeter-scale lamination coupled with cyclic changes in δ13C and δ18O is almost identical with the modern annually-laminated travertine reported from Baishuitai in northern Yunnan Province, implying comparable amplitude of seasonal temperature and precipitation changes to the record of the modern travertine at Baishuitai. Our results do not contradict the previous interpretation of late Eocene wetting and additionally suggest the existence of the late Eocene monsoon climate in the Jianchuan basin.  相似文献   
49.
The isotopic and ionic composition of pure gas hydrate (GH) water was examined for GHs recovered in three gravity cores (165–193 cm length) from the Kukuy K-9 mud volcano (MV) in Lake Baikal. A massive GH sample from core St6GC4 (143–165 cm core depth interval) was dissociated progressively over 6 h in a closed glass chamber, and 11 sequentially collected fractions of dissociated GH water analyzed. Their hydrogen and oxygen isotopic compositions, and the concentrations of Cl and HCO3 remained essentially constant over time, except that the fraction collected during the first 50 minutes deviated partly from this pattern. Fraction #1 had a substantially higher Cl concentration, similar to that of pore water sampled immediately above (135–142 cm core depth) the main GH-bearing interval in that core. Like the subsequent fractions, however, the HCO3 concentration was markedly lower than that of pore water. For the GH water fractions #2 to #11, an essentially constant HCO3 /Cl ratio of 305 differed markedly from downcore pore water HCO3 /Cl ratios of 63–99. Evidently, contamination of the extracted GH water by ambient pore water probably adhered to the massive GH sample was satisfactorily restricted to the initial phase of GH dissociation. The hydrogen and oxygen isotopic composition of hydrate-forming water was estimated using the measured isotopic composition of extracted GH water combined with known isotopic fractionation factors between GH and GH-forming water. Estimated δD of ?126 to ?133‰ and δ18O of ?15.7 to ?16.7‰ differed partly from the corresponding signatures of ambient pore water (δD of ?123‰, δ18O of ?15.6‰) and of lake bottom water (δD of ?121‰, δ18O of ?15.8‰) at the St6GC4 coring site, suggesting that the GH was not formed from those waters. Observations of breccias in that core point to a possible deep-rooted water source, consistent with published thermal measurements for the neighboring Kukuy K-2 MV. By contrast, the pore waters of core St6GC4 and also of the neighboring cores GC2 and GC3 from the Kukuy K-9 MV show neither isotopic nor ionic evidence of such a source (e.g., elevated sulfate concentration). These findings constrain GH formation to earlier times, but a deep-rooted source of hydrate-forming water remains ambiguous. A possible long-term dampening of key deep-water source signatures deserves further attention, notably in terms of diffusion and/or advection, as well as anaerobic oxidation of methane.  相似文献   
50.
The litho‐ and biostratigraphy of the mid‐ to upper‐Cretaceous System around the Yagumaike Pond in the Aridagawa area, Wakayama, Southwest Japan, were investigated. Many Middle to Late Albian megafossils were found in the strata of a block bounded by faults. It was also revealed that the Upper Cretaceous System of other blocks ranges from the Middle Turonian to Santonian. The Albian megafossil assemblage contains few benthic organisms, in contrast with the abundance of nektons found (e.g. cephalopods). Sedimentological observations of the mudstone profiles also indicate that scarcely or weakly bioturbated, well‐laminated mudstone is dominant among the Albian deposits. These results suggest deposition of the Albian mudstone under a dysaerobic to anoxic environment. It is comparable to the extended oceanic anoxia (OAEs) in mid‐Cretaceous time. Albian deposits with similar characteristics are also known to exist in Shikoku, Southwest Japan. A wide sedimentary basin that was directly affected by global environmental events, such as OAEs, seemed to be formed on the Chichibu Belt in the Albian. The Upper Cretaceous strata in the study area are extremely thin, similar to the coeval deposits on the Chichibu Belt in Shikoku. It is suggested that the sedimentation rate in the sedimentary basin on the Chichibu Belt was extremely low during early Late Cretaceous time.  相似文献   
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